PUBLISHED PAPERS:      
         

Rh2 and Ru2
 
502.
J. L. Bear,E. Van Caemelbecke, S. Ngubane, V. Da-Riz, K. M. Kadish, “Electrosynthesis of Rh2(dpf)4(R) Where dpf = N,N’-diphenylformamidinate Anion and R = CH3, C2H5, C3H7, C4H9 or C5H11”, Dalton Transactions, 39, 2486-2490 (2010)
484.
John L. Bear, Baocheng Han, Yulan Li, Siyabonga Ngubane, Eric Van Caemelbecke and Karl M. Kadish, “Synthesis, Spectroscopic Properties and Electrochemistry of Rh2(ap)4(R) where R = CH3 or C6H5 and (ap = 2-anilinopyridinate anion)”, Polyhedron, 28, 1551-1555 (2009)
479.
Karl M. Kadish, Rachel Garcia, Tuan Phan, Julien Wellhoff, Eric Van Caemelbecke, John L. Bear, “Electrochemical and Spectroscopic Characterization of a Series of Mixed-Ligand Diruthenium Compounds”, Inorg. Chem., 47, 11423-11428 (2008)
472.
Minh Nguyen, Tuan Phan, Eric Van Caemelbecke, Wiroaj Kajonkijya, John L. Bear and Karl M. Kadish, “Interconversion Between (3,1) and (4,0) Isomers of Ru2(L)4X Complexes where L is 2-Anilinopyridinate or 2-(2,4,6-Trifluoroanilino)pyridinate Anion and X = Cl- or C=CC5H4N-, Inorg. Chem., 47, 7775-7783 (2008)
465.
Minh Nguyen, Tuan Phan, Eric Van Caemelbecke, Xin Wei, John L. Bear, and Karl M. Kadish, “Synthesis and Characterization of (3,1) Ru2(F3ap)4(NCS) and (3,1) Ru2(F3ap)3(F2Oap)(NCS) where F3ap is the 2-(2,4,6-Trifluoroanilino)pyridinate Anion”, Inorg. Chem., 47, 4392-4400 (2008)
444.
Karl M. Kadish, Minh Nguyen, Eric Van Caemelbecke, and John L. Bear, “Synthesis, Characterization and Electrochemistry of Diruthenium(III,II) and Monoruthenium(III) Complexes Containing Pyridyl-Substituted 2-Anilinopyridinate Ligands” Inorg. Chem, 45, 5996-6003 (2006)
437.
Takashi Nakanishi, Katsuhiko Ariga, Antoine Thuriere, John L. Bear and Karl M. Kadish, “Regulation of Film Electrochemistry and CO Binding of a Diruthenium Complex Embedded in Artificial Lipids on an Electrode”, Thin Solid Films, 499, 349-353 (2006).
413.
S. Materazzi, S. Aquili, C. Bianchetti, G.D. Ascenzo, K.M. Kadish, J.L. Bear, “The Decomposition Mechanism of New Solid-State 4(5)-Aminoimidazole-5(4)-Carboxamide Coordination Compounds”, Thermochim Acta, 409, 145-150 (2004).
412.
Takashi Nakanishi, Antoine Thuriere, John L. Bear and Karl M. Kadish, “Film Electrochemistry of a Diruthenium Complex at an Electrode Modified with Various Matrices in Aqueous Media”, Electrochem. Solid State Lett.,  7, E6-E9 (2004).
404.
Baocheng Han, Jianguo Shao, Zhongping Ou, Tuan D. Phan, Jing Shen, John L. Bear, and Karl M. Kadish, “Synthesis and Characterization of Nitrosyl Riruthenium Complexes.  Interaction between NO and CO across the Metal-Metal Bond”, Inorg. Chem., 43, 7741-7751 (2004).
401.
Karl M. Kadish, Tuan D. Phan, Li-Lun Wang, Lingamallu Girbabu, Antoine Thuriere, Julien Wellhoff, Shurong Huang, Eric Van Caemelbeck, and John L. Bear, “Synthesis, Structural and Electrochemical Characterization of High Oxidation State Diruthenium Complexes Containing Four Identical Unsymmetrical Bridging Ligands”, Inorg. Chem., 43, 4825-4832 (2004).
400.
Zhongping Ou, Karl M. Kadish, Wenbo E, Jianguo Shao, Paul J. Sintic, Kei Ohkubo, Shunichi Fukuzumi, and Maxwell J. Crossley, “Substituent Effects on Site of Electron Transfer During the First Reduction for Gold(III) Porphyrins”, Inorg. Chem., 43, 2078-2086 (2004).
399.
Karl M. Kadish, Tuan D. Phan, Lingamallu Giribabu, Jianguo Shao, Li-Lun Wang, Antonine Thuriere and Eric Van Caemelbecke, and John L. Bear, “Electrochemical and Spectroelectrochemical Characterization of Ru24+ and Ru23+ Complexes under a CO Atmosphere”, Inorg. Chem., 43, 1012-1020 (2004).
395.
Karl M. Kadish, Tuan D. Phan, Lingamallu Giribabu, Eric Van Caemelbecke, and John L. Bear, “Substituent and Isomer Effects on Structural, Spectroscopic and Electrochemical Properties of Dirhodium(III,II) Complexes Containing Four Identical Unsymmetrical Bridging Ligands”, Inorg. Chem., 42, 8663-8673 (2003).
394.
John L. Bear, Wei-Zhong Chen, Boacheng Han, Shurong Huang, Li-Lun Wang, Antoine  Thuriere, Eric Van Caemelbecke,  Karl M. Kadish and Tong Ren, “Cyanide Adducts on the Diruthenium Core of [Ru2(L)4]+ (L = ap, CH3ap, Fap or F3ap) as Potential Supramolecular Synthons.  Electronic Properties and Binding Modes of the Bridging Ligand”, Inorg. Chem., 42, 6230-6240 (2003).
391.
Karl M. Kadish, Li-Lun Wang, Antoine Thuriere, Lingamallu Giribabu, Rachel Garcia, Eric Van Caemelbecke, and John L. Bear “Solvent Effects on the Electrochemistry and Spectroelectrochemistry of Diruthenium Complexes.  Studies of Ru2(L)4Cl where L = 2-CH3ap, 2-Fap and 2,4,6-F3ap and ap is the 2-anilinopyridinate anion”, Inorg. Chem., 42, 8309-8319 (2003).
387.
Roger Guilard, Jean-Michel Barbe, Christine Stern, and Karl M. Kadish, “New Developments in Corrole Chemistry; Special Emphasis on Face-to-Face Bismacrocycles”, in The Porphyrin Handbook, Kadish, K. M.; Smith, K. M. : Guildard, R., Eds., Elesevier, Vol 18, 303-349  (2003).
386.
Karl M. Kadish, Li-Lun Wang, Antoine Thuriere, Eric Van Caemelbecke, and John L. Bear, “Factors Effecting The Electrochemical and Spectroelectrochemical Properties of Diruthenium(III,II) Complexes Containing Four Identical Unsymmetrical Bridging Ligands”, Inorg. Chem, 42, 834-843 (2003).
385.
S. Materazzi, G. D’Ascenzo, S. Aquili, K. M. Kadish and J. L. Bear, “Thermoanalytical characterization of solid-state Co(II)-, Ni(II) and Cu(II)-4(5)-aminoimidazole-5(4)-carboxamide complexes”, Thermochim Acta, 397, 129-134 (2003).
364.
Karl M. Kadish, Baocheng Han, Jianguo Shao, Zhongping Ou, John L. Bear, “Synthesis and Characterization of Diruthenium Complexes in Low Oxidation States.  Formation of Mono-and Bis-CO Adducts”, Inorg. Chem., 40, 6848-6851 (2001).
360.
John L. Bear, Julien Wellhoff, Guy Royal, Eric Van Caemelbecke, Sonia Eapen and Karl  M. Kadish, “Synthesis, Structural Determination and Electrochemistry of Ru2(Fap)4Cl and Ru2(Fap)4(NO)Cl”, Inorg. Chem., 40, 2282-2286, (2001).          
359.
John L. Bear, B. Han, Z. Wu, E. Van Caemelbecke and Karl M. Kadish, “Synthesis, Electrochemistry and Spectroscopic Characterization of Bis-Dirhodium Complexes Linked by Axial Ligands”, Inorg. Chem, 40, 2275-2281, (2001).
358.
John L. Bear, Yulan Li, Baocheng Han, Eric Van Caemelbecke and Karl M. Kadish, “Syntheses and Characterizations of the Diruthenium(III) Complexes Ru2(F4Oap)2(F5ap)2  and Ru2(F4Oap)(F4NCNap)(F5ap)2 Where F4Oap is the 2-(3,4,5,6-Tetrafluoro-2- oxoanilino)pyridinate Anion, F4NCNap is the 2-(3,4,5,6-Tetrafluoro-2- cyanamidoanilino) pyridnate Anion, and F5ap is the 2-(2,3,4,5,6-Pentafluoroanilino)pyridiante Anion”, Inorg. Chem., 40, 182-186, (2001).
354.
Lydie Michaudet, Dominique Fasseur, Roger Guilard, Zhongping  Ou, Karl M. Kadish, Slimane Dahoui, Claude Lecomte, “Synthesis, Characterization and Electrochemistry of Bismuth Porphyrins.  X-ray Crystal Structure of (OEP)Bi(SO3CF3)”, J. Porphyrins Phthalocyanines, 261-270, (2000).
353.
Ikuo Nakanishi, Shunichi Fukuzumi, Jean-Michel Barbe, Roger Guilard and Karl M. Kadish, “Base Control of Electron-Transfer Reactions of Manganese(III) Porphyrins”, Eur. J. Inorg. Chem., 1557-1562 (2000).
346.
John L. Bear, Yulan Li, Jing Cui, Baocheng Han, Eric Van Caemelbecke, Tuan Phan and  Karl M. Kadish, “The Reaction Between the (3,1) Isomer of Ru2(F5ap)4Cl and CN-. Synthesis, Structural Determination and Electrochemistry of Ru2(F5ap)3[μ-(o-NC)F4ap](μ-CN) and Two Geometric Isomers of Ru2(F5ap)4(μ-CN)2”, Inorg. Chem., 39, 857-861 (2000).
305.
John L. Bear, Yulan Li, Baocheng Han, Eric Van Caemelbecke and Karl M. Kadish, "Isomer Effect on the Structure, and Chemical Reactivity of Diruthenium Complexes.  Synthesis and Characterization of (4,0), (3,1) and (2,2) Trans Isomers of Ru2(F5ap)4Cl and Ru2(F5ap)4(Ctriple bondCC6H5)2 Where F5ap is the 2-(2,3,4,5,6-Pentafluoroanilino)-pyridinate Anion”, Inorg. Chem, 36, 5449-5456 (1997).
291.
John L. Bear, Yulan Li, Baocheng Han, Eric Van Caemelbecke, and Karl M. Kadish, "Synthesis and Characterization of a New Type of Diruthenium(III) Complex, Inorg. Chem., 35, 3053-3055 (1996).
290.
J. L. Bear, B. Han, S. Huang and K. M. Kadish, "Effect of Axial Ligands on the Oxidation State, Structure and Electronic Configuration of Diruthenium Complexes.  Synthesis and Characterization of Ru2(dpf)4C1, Ru2(dpf)4 (Ctriple bondCC6H5), Ru2(dpf)4(Ctriple bondCC6H5)2 and Ru2(dpf)4(CN)2 (dpf = N, N'-diphenylformamidinate)”, Inorg. Chem., 35, 3012-3021 (1996).
289.
John L. Bear, Yulan Li, Baocheng Han and Karl M. Kadish, "Synthesis, Molecular Structure and Electrochemistry of a Paramagnetic Diruthenium(III) Complex.  Characterization of  Ru2(hpp)4Cl2, where hpp Is the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinate Ion”, Inorg Chem., 35, 1395-1398 (1996).
255.
Yulan Li, Baocheng Han, Karl M. Kadish and John L. Bear, "A Novel Diamagnetic Diruthenium(III,III) Complex Bridged by Four Unsymmetrical Carboxylate Type Ligands.  Synthesis, Molecular Structure, Electrochemistry and Spectroelectrochemistry of Ru2(pfap)4(Ctriple bondC‑C6H5)2, where pfap is 2,3,4,5,6-Pentafluoro-2-anilinopyridinate”, Inorg. Chem., 32, 4175-4176 (1993).
243.
Jae-Duck Lee, Chao-Liang Yao, Francoise J. Capdevielle, Baocheng Han, John L. Bear and Karl M. Kadish, "Dioxygen Binding to Dirhodium(II,II), (II,III), and (III,III) Complexes.  Spectroscopic Characterization of [Rh2(ap)4(O2)]+, Rh2(ap)4(O2), and [Rh2(ap)4(O2)]‑, where ap = 2-anilino-pyridinate Ion”, Bulletin of the Korean Chemical Society, 14, 195-200 (1993).
214.
J.L. Bear, C.-L. Yao, R.S. Lifsey, J.D. Korp and K.M. Kadish, "Electrochemical Spectroscopic and Structural Characterization of Rh2(dpf)4, Rh2(dpf)4CH3CN) and [Rh2(dpf)4(CH3CN)]ClO4, where dpf = N, N'diphenylformamidinate Anion”, Inorg. Chem., 30, 336-340 (1991).
194.
Chao-Liang Yao, Francoise J. Capdevielle, Karl M. Kadish and John L. Bear, "Thin-Layer Microcell for Transmittance Fourier Transform Infrared Spectroelectrochemistry”, Anal. Chem., 61, 2805-2809 (1989).
183.
J.L. Bear, C.-L. Yao, L.M. Liu, F.J. Capdevielle, J.D. Korp, T.A. Albright, S.-K. Kang and K.M. Kadish, "Synthesis, Molecular Structure and Electrochemical Properties of Two Geometric Isomers of Tetrakis(μ-2-anilinopyridinato)dirhodium Complexes”, Inorg. Chem., 28, 1254-1262 (1989).
178.
J.L. Bear, R.S. Lifsey, L.K. Chau, M.Q. Ahsan, J.D. Korp, M. Chavan and K.M. Kadish, "Structural, Spectroscopic, and Electrochemical Characterization of Tetrakis-μ-(2-pyrrolidinonato)-dirhodium(II) and Tetrakis -μ-(δ-valerolactamato)-dirhodium(II)”, J. Chem. Soc., Dalton Trans., 93-100 (1989).
166.
J.L. Bear, C.-L. Yao, F.J. Capdevielle and K.M. Kadish, "Superoxide Complexes of Tetrakis(μ-2-anilinopyridinato)dirhodium(II,III) and -dirhodium(II,III).  The One-Electron Catalytic Reduction of Dioxygen”, Inorg. Chem., 27, 3782 (1988).
141.
J.L. Bear, L.-M. Liu and K.M. Kadish, "Structural, ESR, and Electrochemical Properties of Two [Rh2(ap)4]+ Geometric Isomers (ap = 2-Anilinopyridinate).  A True Mixed Valent Rh(II)-Rh(III) Complex”, Inorg. Chem., 26, 2927 (1987).
136.
R.S. Lifsey, X.Q. Lin, M. Chavan, M.Q. Ahsan, K.M. Kadish and J.L. Bear, "Reaction of Rh2(O2CCH3)4 with N-Phenylacetamide: Substitution Products and Geometric Isomers”, Inorg. Chem., 26, 830 (1987).
135.
R.S. Lifsey, M.Y. Chavan, L.K. Chau, M.Q. Ahsan, K.M. Kadish and J.L. Bear, "Dirhodium Complexes with Axially and Equatorially Nonequivalent Rhodium Atoms. Characterization of Rh2(tcl)4(tclH) and Rh2(Tcl)4(CO) (tcl = ω-Thiocaprolactamate)”, Inorg. Chem., 26, 822 (1987).
120.
M.Y. Chavan, M.Q. Ahsan, R.S. Lifsey, J.L. Bear and K.M. Kadish, "Reversible CO Binding by Rh2(O2CCH3)n(HNOCCH3)4-n.  A Spectroscopic and Electrochemical Investigation”, Inorg. Chem., 25, 3218 (1986).
115.
J.L. Bear, L.K. Chau, M.Y. Chavan, F. Lefoulon, R.P. Thummel and K.M. Kadish, "Reduction of Dirhodium(II) Complexes of the Type [Rh2(O2CCH3)3(L)]+. An ESR Investigation”, Inorg. Chem., 25, 1514 (1986).
114.
M.Y. Chavan, X.Q. Lin, M.Q. Ahsan, I. Bernal, J.L. Bear and K.M. Kadish, "Nature of the Axial Bond Between Dimethyl Sulfoxide and a Series of Dirhodium Complexes”, Inorg. Chem., 25, 1281 (1986).
108.
J.C. Le, M.Y. Chavan, L.K. Chau, J.L. Bear and K.M. Kadish, "Synthesis and Characteri-zation of Dirhodium Complexes with Four N-N Diphenylbenzamidine Bridging Ligands.  Electrochemical Generation and ESR Properties of [Rh2(N2R2CR)4]n Where R = Phenyl and n = 1 and -1”, J. Am. Chem. Soc., 107, 7195 (1985).
097.
M.Y. Chavan, T.P. Zhu, X.Q. Lin, M.Q. Ahsan, J.L. Bear and K.M. Kadish, "Axial Ligand Dependent Electrochemical and Spectral Properties of a Series of Acetate and Acetamidate Bridged Dirhodium Complexes”, Inorg. Chem., 23, 4538 (1984).
092.
M.Y. Chavan, F.N. Feldmann, X.Q. Lin, J.L. Bear and K.M. Kadish, "Electrochemical Generation of new Dinuclear Ruthenium Acetamidate Complexes “,  Inorg. Chem., 23, 2373 (1984).
080.
J.L. Bear, T.P. Zhu, T. Malinski, A.M. Dennis and K.M. Kadish, "Electrochemical Characterization of a Rhodium(II) Dimer with N-Phenylacetamido Bridging Ligands”, Inorg. Chem., 23, 674 (1984).
078.
T.P. Zhu, M.Q. Ahsan, T. Malinski, K.M. Kadish and J.L. Bear, "Electrochemical Study of a Series of Dirhodium(II) Complexes with Mixed Acetate and Acetamidate Bridging Ions”, Inorg. Chem., 23, 2 (1984).
075.
T. Malinski, D. Chang, F.N. Feldmann, J.L. Bear and K.M. Kadish, "Electrochemical Studies of a Novel Ruthenium(II,III) Dimer, Ru2(HNOCCF3)4Cl”, Inorg. Chem., 22, 3225 (1983).
061.
J. Duncan, T. Malinski, T.P. Zhu, Z.S. Hu, K.M. Kadish and J.L. Bear, "Characterization of Novel Rhodium(II) Dimers with N-Phenylacetamido Bridging Ligands”, J. Am. Chem. Soc., 104, 5507 (1982).
052.
K.M. Kadish, D. Lançon, and J.L. Bear, "Electrochemical Characterization of a Novel Rhodium(II) Dimer, Rh2(ONHCCF3)4”, Inorg. Chem., 21, 2987 (1982).
050.
A.M. Dennis, R.A. Howard, D. Lançon, K.M. Kadish and J.L. Bear "A Dirhodium(II) Complex with Trifluoroacetamidato Ligands”, J. Chem. Soc., Chem. Commun., 399 (1982).
034.
A.M. Dennis, R.A. Howard, K.M.Kadish, J.L. Bear, J. Brace and N. Winograd, "X-ray Photoelectron Spectra of Some Dirhodium Carboxylate Complexes”, Inorg. Chim. Acta, 44, L139 (1980).
026.
K.M. Kadish, K. Das, R. Howard, A. Dennis and J.L. Bear, "Redox Reactions and Anti-tumor Activity of Tetra-μ-Carboxylatodirhodium(II)”, J. Bioelectrochem. Bioenerg., 5, 741 (1978).
023.
K. Das, K.  M. Kadish and J.L. Bear, "Substituent and Solvent Effects on the Electrochemical Properties of Tetra-μ-Carboxylatodirhodium(II)”, Inorg. Chem., 17, 930 (1978).
 
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