"ortho-Arylation of Benzamides"
Shabashov, D.; Daugulis, O.* Org. Lett. 2006,
8, 4947-4949.
"Direct Palladium-Catalyzed ortho-Arylation
of Benzylamines" Lazareva, A.; Daugulis, O.* Org. Lett. 2006,
8, 5211-5213.
"Regioselective Functionalization of Unreactive C-H Bonds"
Daugulis,
O.*; Zaitsev, V. G.; Shabashov, D.; Pham, Q.-N.; Lazareva, A. Synlett,
2006, 15, 3382-3388.
Invited account about our work at the University of Houston.
"Palladium-Catalyzed Arylation of Electron-Rich
Heterocycles with Aryl Chlorides" Chiong, H. A.; Daugulis, O.*
Org. Lett., 2007, 9,
1449-1451.
"Two Methods for Direct ortho-Arylation
of Benzoic Acids" Chiong, H. A.; Pham, Q.-N.; Daugulis, O.* J.
Am. Chem. Soc., 2007, 129,
9879-9884.
"Palladium-Catalyzed Anilide ortho-Arylation
and Subsequent One-Pot Cyclization to Phenanthridines" Shabashov, D.;
Daugulis, O.* J. Org. Chem., 2007,
72, 7720-7725.
"Copper-Catalyzed Arylation of Heterocycle C-H Bonds" Do,
H.-Q.; Daugulis, O.* J. Am. Chem. Soc. 2007,
129, 12404-12405.
"Copper-Catalyzed Arylation and Alkenylation of
Polyfluoroarene C-H Bonds" Do, H.-Q.; Daugulis, O.* J. Am.
Chem. Soc. 2008, 130,
1128-1129.
"Carbon-Hydrogen
Bond Functionalization Approach for the Synthesis of Fluorenones and
ortho-Arylated Benzonitriles" Shabashov, D.; Maldonado, J. M. R.;
Daugulis, O.* J. Org. Chem. 2008,
73, 7818-7821.
"Direct Transition-Metal-Free Intramolecular Arylation of
Phenols" Bajracharya, G.; Daugulis, O.* Org. Lett. 2008,
10, 4625-4628.
"A General Method for Copper-Catalyzed Arylation of Arene
C-H Bonds" Do, H.-Q.; Khan, R. K. M.; Daugulis, O.* J. Am.
Chem. Soc. 2008, 130,
15185-15192
"A Simple Base-Mediated Halogenation of Acidic sp2
C-H
Bonds under Noncryogenic Conditions" Do, H.-Q.; Daugulis, O.* Org.
Lett. 2009, 11,
421-423.
"Palladium
(II) Acetate-Butyldi-1-Adamantyphosphine Catalyzed Arylation of
Electron-Rich Heterocycles. Preparation of 5-Phenyl-2-Isobutylthiazole"
Lazareva, A.; Chiong, H. A.; Daugulis, O.* Org. Synth. 2009,
86, 105.
"Palladium- and Copper-Catalyzed Arylation of
Carbon-Hydrogen Bonds" Daugulis, O.*; Do, H.-Q.; Shabashov, D. Acc.
Chem. Res.2009, 42,
1074-1086. Invited review about our chemistry at UH.
"Direct
Conversion of Carbon-Hydrogen to Carbon-Carbon Bonds by First Row
Transition Metal Catalysis" Kulkarni, A. A.; Daugulis, O.* Synthesis2009, 4087-4109. Invited review.
"In
Situ Generation and Trapping of Aryllithium and Arylpotassium Species
by Halogen, Sulfur, and Carbon Electrophiles" Popov, I.; Do, H.-Q.;
Daugulis, O.* J. Org. Chem. 2009,
74, 8309-8313.
"Palladium and Copper Catalysis in Regioselective,
Intermolecular Coupling of C-H and C-X Bonds" Daugulis, O. Topics
in Current Chemistry2010, 292,
57-84. Invited review.
"Nickel,
Manganese, Cobalt, and Iron-Catalyzed Deprotonative Arene Dimerization"
Truong, T.; Alvarado, J.; Tran, L. D., Daugulis, O.* Org.
Lett. 2010, 12,
1200-1203.
"Evolution
of Catalysts Directed by Genetic Algorithms in a Plug-Based
Microfluidic Device Tested with Oxidation of Methane by Oxygen" Kreutz,
J. E.; Shukhaev, A.; Du, W.; Druskin, S.; Daugulis, O.;* Ismagilov, R.
F.* J. Am. Chem. Soc. 2010,
132, 3128-3132.
"Auxiliary-Assisted Palladium-Catalyzed Arylation and
Alkylation of sp2
and sp3 Carbon-Hydrogen Bonds" Shabashov, D.;
Daugulis, O.* J.
Am. Chem. Soc. 2010, 132,
3965-3972.
"A
General Method for Copper-Catalyzed Arylation of Acidic Arene C-H
Bonds. Preparation of 2-Chloro-5-(3-Methylphenyl)Thiophene" Alvarado,
J.; Do, H.-Q.; Daugulis, O.* Org. Synth. 2010,
87, 184-191.
"Copper-Catalyzed Cyanation of Heterocycle Carbon−Hydrogen
Bonds" Do, H.-Q.; Daugulis, O.* Org. Lett. 2010,
12, 2517-2519.
"Iron-Catalyzed Heterocycle and Arene Deprotonative
Alkylation" Tran, L. D.; Daugulis, O.* Org. Lett. 2010,12, 4277-4279.
"Palladium-Catalyzed Indole, Pyrrole, and Furan Arylation
by Aryl Chlorides" Nadres, E. T.; Lazareva, A.; Daugulis, O.*
J. Org. Chem.2011, 76,
471-483.
"Base-Mediated Intermolecular sp2
C-H Bond Arylation via
Benzyne Intermediates" Truong, T.; Daugulis, O.* J. Am.
Chem. Soc. 2011, 133,
4243-4245.
"Copper-Catalyzed Arylation of 1H-Perfluoroalkanes" Popov,
I.; Lindeman, S.; Daugulis, O.* J. Am. Chem. Soc. 2011,
133, 9286-9289.
"Transition-Metal-Free Alkynylation of Aryl Chlorides"
Truong, T.; Daugulis, O.* Org. Lett. 2011,
13, 4172-4175.
"A General Method for Copper-Catalyzed Arene
Cross-Dimerization" Do, H.-Q.; Daugulis, O.* J. Am. Chem.
Soc.2011,
133,
13577-13586.
"Intermolecular Direct Arylation of Five-Membered Ring
Heterocycles by Non-Activated Aryl Chlorides" Daugulis, O. Chem.
Heterocycl. Compd.2012, 48, 21-26.
Invited review.
"Heterocycle Synthesis via Direct C-H/N-H Coupling" Nadres,
E. T.; Daugulis, O.* J. Am. Chem. Soc. 2012,
134, 7-10.
"Nonnatural Amino Acid Synthesis by Carbon-Hydrogen Bond
Functionalization Methodology" Tran, L. D.; Daugulis, O.* Angew.
Chem., Int. Ed.2012, 51, 5188-5191.
"Copper-Catalyzed
Homodimerization of
Nitronates and Enolates under an Oxygen Atmosphere" Do, H.-Q.; Tran-Vu,
H.; Daugulis, O.* Organometallics 2012, 31, 7816-7818.
"Directed Functionalization of
C-H Bonds – now also meta-Selective" Truong, T.; Daugulis,
O.* Angew. Chem., Int. Ed.2012, 51, 11677-11679.
Highlight.
"Copper-Promoted Sulfenylation of sp2
C-H Bonds"
Tran, L. D.; Popov, I.; Daugulis, O.* J.
Am. Chem.
Soc. 2012, 134, 18237-18240.
"Direct Intermolecular Aniline Arylation via
Benzyne Intermediates" Truong, T.; Daugulis, O.* Org.
Lett. 2012,
14,
5964-5967.
"Divergent Reaction Pathways for Phenol Arylation
by Arynes: Synthesis of Helicenes and 2-Arylphenols" Truong, T.;
Daugulis, O.* Chem. Sci. 2013, 4, 531-535.
"Directed
Amination of Non-Acidic Arene CH Bonds by a Copper–Silver Catalytic
System" Tran, L. D.; Roane, J.; Daugulis, O.* Angew.
Chem., Int. Ed. 2013,
52,
6043-6046.
"Copper-Catalyzed,
Directing Group-Assisted Fluorination of Arene and Heteroarene
C−H
Bonds" Truong, T.; Klimovica, K.; Daugulis, O.* J.
Am. Chem. Soc. 2013, 135,
9342-9345. C&E News Perspective.
"Synthesis of Highly Branched Polyethylene Using
“Sandwich” (8-p-Tolyl Naphthyl α-Diimine)Nickel(II) Catalysts" Zhang,
D.; Nadres, E. T.; Brookhart, M.*; Daugulis, O.* Organometallics 2013, 32, 5136-5143.
"Scope and Limitations of Auxiliary-Assisted,
Palladium-Catalyzed Arylation and Alkylation of sp2
and sp3
C-H Bonds" Nadres, E. T.; Santos, G. I. F.; Shabashov, D.; Daugulis,
O.* J. Org. Chem. 2013, 78, 9689-9714.
"Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon
Dioxide" Tran-Vu, H.; Daugulis, O.* ACS Catalysis 2013, 3, 2417-2420.
"Copper-Catalyzed Etherification of Arene C-H Bonds" Roane,
J.; Daugulis, O.* Org.
Lett. 2013, 15, 5842-5845.
"Secondary
Alkene Insertion and Precision Chain-Walking: A New Route to
Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare
Catalytic Events" Vaidya, T.; Klimovica, K.; LaPointe, A.;
Keresztes, I.; Lobkovsky, E. B.; Daugulis, O.*; Coates, G.* J.
Am. Chem.
Soc. 2014,
136,
7213-7216.
"A
General Method for Functionalized Polyaryl Synthesis via Aryne
Intermediates" Truong, T.; Mesgar, M.; Le, K. K. A.; Daugulis, O.* J. Am. Chem. Soc. 2014,
136, 8568-8576.
"Cobalt-Catalyzed,
Aminoquinoline-Directed sp2 C-H
Bond Alkenylation by Alkynes" Grigorjeva,
L.; Daugulis, O.* Angew.
Chem., Int. Ed. 2014,
53,
10209-10212.
"Cobalt-Catalyzed,
Aminoquinoline-Directed
Coupling of sp2 C-H Bonds with Alkenes" Grigorjeva,
L.; Daugulis, O.* Org.
Lett. 2014, 16, 4684-4687.
ACS
Editors Choice for August 22.
"Cobalt-Catalyzed
Direct Carbonylation of
Aminoquinoline Benzamides" Grigorjeva, L.;
Daugulis, O.* Org. Lett.
2014, 16, 4688-4690.
"Thermally robust
and porous noncovalent organic framework with high affinity for
fluorocarbons and Freons"
Chen, T.-H.; Popov, I.; Kaveevivitchai,
W.; Chuang,
Y.-C.; Chen, Y.-S.; Daugulis, O.; Jacobson,
A.
J.; Miljanić, O.* Nat. Comm. 2014, 5, 5131. PhysOrgChem
Perspective.C&E
News Perspective.
"Living
Polymerization of Ethylene and Copolymerization of Ethylene/Methyl
Acrylate Using "Sandwich" Diimine Palladium Catalysts"Allen, K. E.;
Campos, J.; Daugulis, O.; Brookhart, M.* ACS Catalysis2015, 5, 456-464.
"Synthesis
of Branched Ultra-High-Molecular-Weight Polyethylene Using Highly
Active Neutral, Single-Component Ni(II) Catalysts" Chen, Z.; Mesgar,
M.; White, P.; Daugulis, O.*; Brookhart, M.* ACS Catalysis2015, 5, 631-636.
"Macrocycle
Embrace: Encapsulation of Fluoroarenes by m-Phenylene Ethynylene Host"
Popov, I.; Chen, T.-H.; Belyakov, S.; Daugulis,
O.; Wheeler, S. E.; Miljanic, O. S.* Chemistry - A European Journal 2015, 21, 2750-2754.
"Cobalt-Promoted
Dimerization of Aminoquinoline Benzamides" Grigorjeva, L.; Daugulis, O.* Org.
Lett. 2015, 17, 1204-1207.
"Bidentate,
Monoanionic Auxiliary-Directed Functionalization of Carbon-Hydrogen
Bonds" Daugulis, O.*; Roane, J.; Tran, L. D. Acc.Chem.Res. 2015, 48,
1053-1064. Invited
review about our chemistry at UH.
"Cobalt-Catalyzed, Aminoquinoline-Directed
Functionalization of Phosphinic Amide sp2
C−H Bonds" Nguyen, T. T.; Grigorjeva, L.; Daugulis, O.* ACS Catalysis2016,6, 551-554.
"A
Career in Catalysis: Maurice Brookhart"
Daugulis, O.; MacArthur, A. H. R.*; Rix, F. C.;
Templeton, J. L. ACS
Catalysis2016, 6,
1518-1532. Account about carrer of Prof. M. Brookhart.
"A General Method for Aminoquinoline-Directed,
Copper-Catalyzed sp2
CH Bond Amination " Roane, J.; Daugulis, O.* J.
Am. Chem.
Soc. 2016,138, 4601-4607.
"Silylaryl Halides Can Replace Triflates as Aryne
Precursors" Mesgar, M.; Daugulis, O.* Org. Lett.2016,
18, 3910–3913.
"Synthesis
and Properties of “ Sandwich ” Diimine-Coinage Metal Ethylene
Complexes" Klimovica, K.; Kirschbaum, K.; Daugulis, O.* Organometallics2016, 35, 2938−2943.
"Mechanistic
Studies of Pd(II)-Catalyzed Copolymerization of Ethylene and
Vinylalkoxysilanes: Evidence for a β‑Silyl Elimination Chain Transfer
Mechanism" Chen, Z.; Liu, W.; Daugulis, O.*; Brookhart, M.*. J. Am. Chem. Soc. 2016, 138, 16120-16129.
"Oligomerization of Ethylene Using a Diphosphine Palladium
Catalyst" Bézier, D.; Daugulis, O.*; Brookhart, M.* Organometallics 2017, 36, 443-447.
"Palladium-Catalyzed Pyrazole-Directed sp3
C-H Bond Arylation for the Synthesis of beta-Phenethylamines"
Gulia, N.; Daugulis, O.* Angew.
Chem., Int. Ed. 2017,
56, 3630–3634.
"Palladium-Catalyzed,
Aminoquinoline-Directed Arylation of Phosphonamidate and Phosphinic
Amide sp3
C-H Bonds" Nguyen, T. T.; Daugulis, O.* Chem. Commun. 2017, 53, 4609-4611.
"Aminoquinoline-Directed,
Cobalt-Catalyzed Carbonylation of Sulfonamide sp2
C-H Bonds"
Nguyen,
T. T.; Grigorjeva, L.; Daugulis, O.* Chem. Commun. 2017, 53, 5136-5138.
"Understanding
the Insertion Pathways and Chain
Walking Mechanisms of α-Diimine Nickel Catalysts for α-Olefin
Polymerization: A
13C NMR Spectroscopic Investigation" O’Connor, K.
S.; Lamb, J.
R.; Vaidya,
T.; Keresztes,
I.; Klimovica,
K.; LaPointe, A.
M.; Daugulis,
O.; Coates, G. W.* Macromolecules 2017,50,
7010-7027.
"Polymerization of Ethylene
Catalyzed by Phosphine-Iminophosphorane Palladium Complexes"
Bézier, D.; Daugulis, O.*; Brookhart, M.* Organometallics2017, 36, 2947–2951.
"Synthesis
of 1,2-Bis-(Trifluoromethylthio)arenes via Aryne Intermediates"
Mesgar, M.; Daugulis, O.* Org.
Lett. 2017, 19, 4247–4250.
"Nickel-Catalyzed
Copolymerization of Ethylene and Vinyltrialkoxysilanes: Catalytic
Production of
Cross-linkable Polyethylene and Elucidation of the Chain Growth
Mechanism" Chen,
Z.; Leatherman, M. D.; Daugulis, O.*; Brookhart, M.* J. Am. Chem. Soc. 2017,139, 16013–16022.
"Dissecting
Porosity in Molecular Crystals: Influence
of Geometry, Hydrogen Bonding, and [π···π] Stacking on the Solid-State
Packing" Le,
H. T. M.; Chen, T.-H.;
Yu-Sheng Chen, Y.-S.; Daugulis, O.; Hashim, M. I.;
Hsu, C.-W.; Jacobson, A. J.; Kaveevivitchai, W.;
Liang, X.; Makarenko, T.; Miljanić, O. Š.*;Popov, I.; Wang, X.; Wu, C.-H.; Wu, J. I. J. Am. Chem. Soc.2018, 140, 6014−6026.
"Synthesis
of Unsymmetrical 2,6-Diarylanilines by Palladium-Catalyzed C-H Bond
Functionalization Methodology" Kwak, S. H.; Gulia, N.; Daugulis,
O.* J. Org.
Chem.2018,
83,
5844−5850.
"New
Hindered Amide Base for Aryne Insertion into
Si-P, Si-S, Si-N, and C-C Bonds" Mesgar, M.;
Nguyen-Le, J.; Daugulis, O.* J. Am. Chem. Soc.2018, 140, 13703-13710.
"A
highly active Ni(II)-triadamantylphosphine catalyst for
ultrahigh-molecular-weight polyethylene synthesis"
Kocen, A. L.; Brookhart, M.*; Daugulis, O.* Nat. Comm. 2019, 10, 438.
"Solvation-Dependent
Switching of Solid-state Luminescence of a Fluorinated Aromatic
Tetrapyrazole" Zhang, Z.; Lieu, T.; Wu, C.-H.; Wang, X.; Wu, J. I.-C.;
Daugulis, O.; Miljanic, O.* Chem.
Commun. 2019,55,
9387-9390.
"1,2-Bis(arylthio)arene Synthesis via Aryne
Intermediates" Mesgar, M.; Nguyen-Le, J.; Daugulis, O.*
Chem. Commun. 2019,55,
9467-9470.
"1-Aminopyridinium Ylides as Monodentate Directing Groups
for sp3 CH Bond Functionalization" Le,. K. K.
A.; Nguyen, H.; Daugulis, O.* J. Am. Chem. Soc.2019,
141,14728-14735.
"N-Aminopyridinium
Ylide-Directed Copper-Promoted Amination of sp2
C-H Bonds" Kwak, S. H.; Daugulis, O.* J. Org. Chem. 2019,
84,13022-13032.
"Ethylene
Polymerization With Ni(II) Diimine Complexes Generated from
8-Halo-1-naphthylamines. The Role of Equilibrating Syn/Anti
Diastereomers in Determining Polymer Properties"Wang, B.;
Daugulis, O.*; Brookhart, M.* Organometallics2019, 38, 4658-4668.
"New
Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of
Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled
Polymerization and Mechanistic Studies of Chain Propagation"
Tran,
Q. H.; Brookhart, M.*; Daugulis, O.* J. Am. Chem. Soc.2020,
142, 7198-7206.
"N-Iminopyridinium
Ylide-Directed, Cobalt-Catalyzed Coupling of sp2
C-H Bonds with
Alkynes" Kwak,
S. H.; Daugulis, O.* Chem.
Commun. 2020,
56,
11070-11073.
"Unsaturated
Alcohols as Chain-transfer Agents in Olefin Polymerization: Synthesis
of
Aldehyde End-capped Oligomers and Polymers" Han, X.-W.; Daugulis, O.*; Brookhart, M.* J.
Am. Chem. Soc.2020,
142,
15431–15437.
JACS Spotlight.
"N-Aminopyridinium
Ylide-Directed, Copper-Promoted Thiolation of Arene C-H Bonds"
Nguyen, H.; Daugulis, O.* J.
Org. Chem. 2020,
85,
13069-13079.
"Cationic
α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene
Substituents: Highly Active Ethylene Polymerization Catalysts and
Mechanistic Studies of Syn/Anti Isomerization" Tran, Q. H.; Wang,
X.; Brookhart,
M.*; Daugulis, O.* Organometallics2020, 39, 4704-4716.
"2,4,6-Triphenylpyridinium:
A Bulky, Highly Electron-Withdrawing Substituent Which Enhances
Properties of Nickel(II) Ethylene Polymerization Catalysts" Janeta, M.;
Heidlas, J. X.; Daugulis, O.*; Brookhart, M.* Angew. Chem., Int. Ed. 2021, 60, 4566–4569. Hot Paper.
"Synthesis
of End-functionalized Poly(norbornene)s and Poly(ethylidene norbornene)s Using
a Pd(II) Catalyst in Combination with Chain Transfer Agents" Han, X.-W.; Daugulis, O.*; Brookhart, M.* Organometallics 2021, 40, 2709-2715.
"In Situ ortho-Lithiation/Functionalization of Pentafluorosulfanyl Arenes" Le, T. V.; Daugulis, O.* Chem. Commun. 2022, 58, 537–540.
"Synthesis
and Optical Properties of Fluorinated Tetraphenylethylenes" Zhang, Z.;
Lieu, T.; Wang, X.; Daugulis, O.*; Miljanic, O.* ChemPhotoChem e202200011. https://doi.org/10.1002/cptc.202200011
"Sandwich” Diimine-Copper Catalysts for C-H
Functionalization by Carbene Insertion" Klimovica, K.; Heidlas, J. X.; Romero, I.; Le, T. V.; Daugulis, O.* Angew.
Chem., Int. Ed. 2022, 61, e202200334. https://doi.org/10.1002/anie.202200334
"Copper Iodide-Mediated Synthesis of α-Diimine Ligands from Bis(imidoyl
Chlorides) and Arylstannanes" Lieu, T.; Daugulis, O.* Organometallics 2022, 41, 3249-3256.
"8-Aminoquinoline" First update. Roane, J.; Daugulis, O.; Le, T. V. Encyclopaedia of Reagents for Organic Synthesis doi.org/10.1002/047084289X.rn01830.
"Polymerization of Terminal Acetylenes by a Bulky Monophosphine-Palladium Catalyst" Chen, Z.-H.; Daugulis, O.*; Brookhart, M.* Organometallics2023, 42, 235-239.
""Sandwich"
Diimine-Copper Catalyzed Trifluoroethylation and Pentafluoropropylation
of Unactivated C(sp3)-H Bonds by Carbene Insertion" Le, T. V.; Romero,
I.; Daugulis, O.* Chem.-Eur. J. 2023, 29, e202301672. https://doi.org/10.1002/chem.202301672.
"Trifluoroethylation and Pentafluoropropylation of C(sp3)-H Bonds" Le, T. V.; Ramachandru, G. G.; Daugulis, O.* Chem.-Eur. J. , in press.